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Isolation of Tetracyano‐Naphthalenediimide and Its Stable Planar Radical Anion
Author(s) -
Kumar Yogendra,
Kumar Sharvan,
Mandal Kalyanashis,
Mukhopadhyay Pritam
Publication year - 2018
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201807836
Subject(s) - chemistry , intramolecular force , supramolecular chemistry , ion , hydrogen bond , radical ion , planar , electrochemistry , crystallography , photochemistry , stereochemistry , molecule , organic chemistry , crystal structure , computer graphics (images) , electrode , computer science
Reported herein is the first isolation of tetracyano‐naphthalenediimide [NDI(CN) 4 ] and its radical anion, and structural elucidation through spectroscopic and X‐ray diffraction studies. The radical anion shows remarkable stability and was purified by chromatography, which is unique for planar radical anions. The stability results from multiple hydrogen bonds to the counter ion and through an array of intramolecular noncovalent interactions. The radical anion revealed one of the strongest NDI π–π interactions (3.268 Å). Electrochemical studies of [NDI(CN) 4 ] confirm its extraordinarily low‐lying LUMO (−5.0 eV), rendering it one of the strongest electron‐deficient planar π systems to be isolated. The manifold potential, which remained unknown to date, can now be explored for these open‐ and closed‐shell planar π systems.