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Inside Cover: Synthesis of an All‐Ferric Cuboidal Iron–Sulfur Cluster [Fe III 4 S 4 (SAr) 4 ] (Angew. Chem. Int. Ed. 36/2018)
Author(s) -
Moula Golam,
Matsumoto Tsuyoshi,
Miehlich Matthias E.,
Meyer Karsten,
Tatsumi Kazuyuki
Publication year - 2018
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201806879
Subject(s) - sulfur , ferric , chemistry , cluster (spacecraft) , int , cover (algebra) , crystallography , ferredoxin , inorganic chemistry , mechanical engineering , organic chemistry , computer science , engineering , programming language , operating system , biochemistry , enzyme
The “highly oxidized” all‐ferric [Fe 4 S 4 (Sar) 4 ] cluster has been synthesized and characterized, as reported by K. Tatsumi et al. in their Communication on page 11594 ff. Isolation of this all‐Fe III cluster indicates the interesting possibility that the Fe 4 S 4 ferredoxin in nature could also exist in the all‐ferric state.