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Room‐Temperature Functionalization of N 2 to Borylamine at a Molybdenum Complex
Author(s) -
Espada Maria F.,
Bennaamane Soukaina,
Liao Qian,
SaffonMerceron Nathalie,
Massou Stéphane,
Clot Eric,
Nebra Noel,
FustierBoutig Marie,
Mézailles Nicolas
Publication year - 2018
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201805915
Subject(s) - surface modification , molybdenum , hydride , intermolecular force , chemistry , metal , polymer chemistry , stereochemistry , crystallography , inorganic chemistry , medicinal chemistry , molecule , organic chemistry
Intermolecular, stepwise functionalization by BH bonds of a (triphosphine)Mo IV –nitrido complex generated by N 2 splitting is reported. The imido–hydride and di‐hydride–amido Mo IV complexes have been isolated and characterized. Addition of PinBH to the [Mo(H) 2 (N(BPin) 2 )] + complex at room temperature results in the liberation of borylamines from the metal center.