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Back Cover: Ligand‐Unsupported Cuprophilicity in the Preparation of Dodecacopper(I) Complexes and Raman Studies (Angew. Chem. Int. Ed. 31/2018)
Author(s) -
Harisomayajula N. V. Satyachand,
Wu BoHan,
Lu DuanYen,
Kuo TingShen,
Chen IChia,
Tsai YiChou
Publication year - 2018
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201805481
Subject(s) - raman spectroscopy , intermolecular force , monomer , int , cover (algebra) , crystallography , ligand (biochemistry) , chemistry , materials science , stereochemistry , molecule , physics , computer science , organic chemistry , engineering , optics , mechanical engineering , biochemistry , receptor , operating system , polymer
Cuprophilicity is still under debate, while aurophilicity and argentophilicity are well recognized. I.‐C. Chen, Y.‐C. Tsai, and co‐workers report in their Communication on page 9925 ff. the synthesis and characterization of two dodecacopper(I) chain‐like complexes via intermolecular Cu–Cu coupling of two linear hexacopper monomers. Their structures were determined by X‐ray crystallography and the unsupported cuprophilic interactions were corroborated by Raman spectroscopy.