Sensing Uranyl(VI) Ions by Coordination and Energy Transfer to a Luminescent Europium(III) Complex | Zendy

Harvey Peter | Zendy; at Aline | Zendy; PlatasIglesias Carlos | Zendy; Natrajan Louise S. | Zendy; Charbonnière Loïc J. | Zendy

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Sensing Uranyl(VI) Ions by Coordination and Energy Transfer to a Luminescent Europium(III) Complex

Author(s) -

Harvey Peter,

at Aline,

PlatasIglesias Carlos,

Natrajan Louise S.,

Charbonnière Loïc J.

Publication year - 2018

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201805316

Subject(s) - uranyl , europium , lanthanide , ion , chemistry , fluorescence , luminescence , energy transfer , inorganic chemistry , coordination complex , uranium , materials science , metallurgy , organic chemistry , physics , optoelectronics , quantum mechanics , molecular physics , metal

The release of uranyl(VI) is a hazardous environmental issue, with limited ways to monitor accumulation in situ. Here, we present a method for the detection of uranyl(VI) ions through the utilization of a unique fluorescence energy transfer process to europium(III). Our system displays the first example of a “turn‐on” europium(III) emission process with a small, water‐soluble lanthanide complex triggered by uranyl(VI) ions.

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