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Surfactant Assembly within Pickering Emulsion Droplets for Fabrication of Interior‐Structured Mesoporous Carbon Microspheres
Author(s) -
Liu Dawei,
Xue Nan,
Wei Lijuan,
Zhang Ye,
Qin Zhangfeng,
Li Xuekuan,
Binks Bernard P.,
Yang Hengquan
Publication year - 2018
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201805022
Subject(s) - microsphere , materials science , mesoporous material , nanotechnology , fabrication , pulmonary surfactant , pickering emulsion , emulsion , chemical engineering , spheres , carbon fibers , nanoparticle , composite material , chemistry , aerospace engineering , engineering , organic chemistry , catalysis , medicine , alternative medicine , pathology , composite number
Large‐sized carbon spheres with controllable interior architecture are highly desired, but there is no method to synthesize these materials. Here, we develop a novel method to synthesize interior‐structured mesoporous carbon microspheres (MCMs), based on the surfactant assembly within water droplet‐confined spaces. Our approach is shown to access a library of unprecedented MCMs such as hollow MCMs, multi‐chambered MCMs, bijel‐structured MCMs, multi‐cored MCMs, “solid” MCMs, and honeycombed MCMs. These novel structures, unattainable for the conventional bulk synthesis even at the same conditions, suggest an intriguing effect arising from the droplet‐confined spaces. This synthesis method and the hitherto unfound impact of the droplet‐confined spaces on the microstructural evolution open up new horizons in exploring novel materials for innovative applications.