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An Anionic Aluminium Nucleophile
Author(s) -
Hinz Alexander,
Breher Frank
Publication year - 2018
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201804930
Subject(s) - nucleophile , reactivity (psychology) , aluminium , metathesis , benzene , chemistry , salt metathesis reaction , organic chemistry , medicinal chemistry , polymer chemistry , catalysis , polymerization , medicine , polymer , alternative medicine , pathology
The first stable anionic aluminium nucleophile was isolated by Goicoechea, Aldridge and co‐workers. The aluminyl compound showed very high reactivity in metathesis reactions as well as in the oxidative addition of substrates such as dihydrogen and benzene, which opens up new perspectives in main group chemistry.