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Nanofluidic Ion Transport and Energy Conversion through Ultrathin Free‐Standing Polymeric Carbon Nitride Membranes
Author(s) -
Xiao Kai,
Giusto Paolo,
Wen Liping,
Jiang Lei,
Antonietti Markus
Publication year - 2018
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201804299
Subject(s) - materials science , carbon nitride , membrane , nanotechnology , desalination , ionic bonding , ion , ion transporter , energy transformation , chemistry , organic chemistry , biochemistry , physics , photocatalysis , thermodynamics , catalysis
Ions transport through confined space with characteristic dimensions comparable to the Debye length has many applications, for example, in water desalination, dialysis, and energy conversion. However, existing 2D/3D smart porous membranes for ions transport and further applications are fragile, thermolabile, and/or difficult to scale up, limiting their practical applicability. Now, polymeric carbon nitride alternatively allows the creation of an ultrathin free‐standing carbon nitride membrane (UFSCNM), which can be fabricated by simple CVD polymerization and exhibits excellent nanofluidic ion‐transport properties. The surface‐charge‐governed ion transport also endows such UFSCNMs with the function of converting salinity gradients into electric energy. With advantages of low cost, facile fabrication, and the ease of scale up while supporting high ionic currents, UFSCNM can be considered as an alternative for energy conversion systems and new ionic devices.