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Simple Synthesis of Functionalized 2‐Phosphanaphthalenes
Author(s) -
Mei Yanbo,
Wu DongJun,
Borger Jaap E.,
Grützmacher Hansjörg
Publication year - 2018
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201802242
Subject(s) - electrophile , phthalazine , chemistry , combinatorial chemistry , coordination complex , transition metal , sodium , metal , polymer chemistry , organic chemistry , catalysis
A simple synthesis of sodium 2‐phosphanaphthalene‐3‐olate ( 1 ) based on the extrusion of N 2 from phthalazine using Na[OCP] is reported. This heterocycle can be readily functionalized at the negatively charged oxygen center using a variety of electrophilic substrates. The coordination chemistry of both 1 and its neutral derivatives was explored, revealing their facile use as P‐donor ligands for late‐transition‐metal complexes.