Brønsted Acid Enabled Nickel‐Catalyzed Hydroalkenylation of Aldehydes with Styrene and its Derivatives | Zendy

Han XingWang | Zendy; Zhang Tao | Zendy; Zheng YanLong | Zendy; Yao WeiWei | Zendy; Li JiangFei | Zendy; Pu YouGe | Zendy; Ye Mengchun | Zendy; Zhou QiLin | Zendy

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Brønsted Acid Enabled Nickel‐Catalyzed Hydroalkenylation of Aldehydes with Styrene and its Derivatives

Author(s) -

Han XingWang,

Zhang Tao,

Zheng YanLong,

Yao WeiWei,

Li JiangFei,

Pu YouGe,

Ye Mengchun,

Zhou QiLin

Publication year - 2018

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201801817

Subject(s) - styrene , aldehyde , catalysis , brønsted–lowry acid–base theory , yield (engineering) , alkene , chemistry , nickel , allylic rearrangement , selectivity , organic chemistry , materials science , copolymer , polymer , metallurgy

A Brønsted acid enabled nickel‐catalyzed hydroalkenylation of aldehydes and styrene derivatives has been developed. The Brønsted acid acts as a proton shuttle to transfer a proton from the alkene to the aldehyde, thereby leading to an economical and byproduct‐free coupling. A series of synthetically useful allylic alcohols were obtained through one‐step reactions from readily available styrene derivatives and aliphatic aldehydes in up to 88 % yield and with high linear selectivity.

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