A [3]Rotaxane Host Selects Between Stereoisomers | Zendy

Denis Mathieu | Zendy; Goldup Stephen Michael | Zendy

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A [3]Rotaxane Host Selects Between Stereoisomers

Author(s) -

Denis Mathieu,

Goldup Stephen Michael

Publication year - 2018

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201800665

Subject(s) - rotaxane , stereoselectivity , stereochemistry , host (biology) , chemistry , binding site , biology , molecule , genetics , biochemistry , organic chemistry , supramolecular chemistry , catalysis

What has it got in its pockets? A new approach to the selective binding and reporting of stereoisomers using mechanical bonding to produce a well‐defined three‐dimensional binding pocket was recently reported by Beer and co‐workers. The highly stereoselective binding of stereoisomers by the reported [3]rotaxane suggest that the use of the mechanical bond to engineer a binding pocket has great potential for the development of stereoselective hosts.

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