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From Linear to Angular Isomers: Achieving Tunable Charge Transport in Single‐Crystal Indolocarbazoles Through Delicate Synergetic CH/NH⋅⋅⋅π Interactions
Author(s) -
Jiang Hui,
Hu Peng,
Ye Jun,
Chaturvedi Apoorva,
Zhang Keke K.,
Li Yongxin,
Long Yi,
Fichou Denis,
Kloc Christian,
Hu Wenping
Publication year - 2018
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201713288
Subject(s) - intermolecular force , polaron , density functional theory , coupling (piping) , crystal (programming language) , hydrogen bond , charge (physics) , chemical physics , chemistry , single crystal , materials science , crystallography , computational chemistry , molecule , physics , organic chemistry , quantum mechanics , computer science , metallurgy , programming language , electron
Weak intermolecular interaction in organic semiconducting molecular crystals plays an important role in molecular packing and electronic properties. Here, four five‐ring‐fused isomers were rationally designed and synthesized to investigate the isomeric influence of linear and angular shapes in affecting their molecular packing and resultant electronic properties. Single‐crystal field‐effect transistors showed mobility order of 5,7‐ICZ (3.61 cm 2 V −1 s −1 ) >5,11‐ICZ (0.55 cm 2 V −1 s −1 ) >11,12‐ICZ (ca. 10 −5 cm 2 V −1 s −1 ) and 5,12‐ICZ (ca. 10 −6 cm 2 V −1 s −1 ). Theoretical calculations based on density functional theory (DFT) and polaron transport model revealed that 5,7‐ICZ can reach higher mobilities than the others thanks to relatively higher hole transfer integral that links to stronger intermolecular interaction due to the presence of multiple NH⋅⋅⋅π and CH⋅⋅⋅π(py) interactions with energy close to common NH⋅⋅⋅N hydrogen bonds, as well as overall lower hole‐vibrational coupling owing to the absence of coupling of holes to low frequency modes due to better π conjugation.