Active Molybdenum‐Based Anode for Dehydrogenative Coupling Reactions | Zendy

Beil Sebastian B. | Zendy; Müller Timo | Zendy; Sillart Sydney B. | Zendy; Franzmann Peter | Zendy; Bomm Alexander | Zendy; Holtkamp Michael | Zendy; Karst Uwe | Zendy; Schade Wolfgang | Zendy; Waldvogel Siegfried R. | Zendy

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Active Molybdenum‐Based Anode for Dehydrogenative Coupling Reactions

Author(s) -

Beil Sebastian B.,

Müller Timo,

Sillart Sydney B.,

Franzmann Peter,

Bomm Alexander,

Holtkamp Michael,

Karst Uwe,

Schade Wolfgang,

Waldvogel Siegfried R.

Publication year - 2018

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201712718

Subject(s) - anode , molybdenum , reagent , stoichiometry , materials science , chemistry , combinatorial chemistry , inorganic chemistry , chemical engineering , organic chemistry , electrode , engineering

A new and powerful active anode system that can be operated in 1,1,1,3,3,3‐hexafluoro‐2‐propanol (HFIP) has been discovered. In HFIP the molybdenum anode forms a compact, conductive, and electroactive layer of higher‐valent molybdenum species. This system can replace powerful but stoichiometrically required Mo V reagents for the dehydrogenative coupling of aryls. This electrolytic reaction is more sustainable and allows the conversion of a broad scope of activated arenes.

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