Cover Picture: The Weakly Coordinating Tris(trichlorosilyl)silyl Anion (Angew. Chem. Int. Ed. 52/2017) | Zendy

Olaru Marian | Zendy; Hesse Maxie F. | Zendy; Rychagova Elena | Zendy; Ketkov Sergey | Zendy; Mebs Stefan | Zendy; Beckmann Jens | Zendy

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Cover Picture: The Weakly Coordinating Tris(trichlorosilyl)silyl Anion (Angew. Chem. Int. Ed. 52/2017)

Author(s) -

Olaru Marian,

Hesse Maxie F.,

Rychagova Elena,

Ketkov Sergey,

Mebs Stefan,

Beckmann Jens

Publication year - 2017

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Reports

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201712183

Subject(s) - deprotonation , acetonitrile , chemistry , ion , carbene , brønsted–lowry acid–base theory , organic chemistry , catalysis

HSi(SiCl3)3is a strong Brønsted acid … … that is more than 43 times stronger than HSiMe 3 and even slightly stronger than HCl in acetonitrile. In their Communication on page 16490 ff., S. Ketkov, S. Mebs, J. Beckmann, and co‐workers show that the deprotonation of HSi(SiCl 3 ) 3 with an N‐heterocyclic carbene leads to the formation of Si(SiCl 3 ) 3 − , a weakly coordinating anion

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