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Catalytic CO Oxidation by O 2 Mediated by Noble‐Metal‐Free Cluster Anions Cu 2 VO 3 – 5 −
Author(s) -
Wang LiNa,
Li XiaoNa,
Jiang LiXue,
Yang Bin,
Liu QingYu,
Xu HongGuang,
Zheng WeiJun,
He ShengGui
Publication year - 2018
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201712129
Subject(s) - catalysis , bimetallic strip , chemistry , noble metal , heteronuclear molecule , vanadium oxide , oxide , inorganic chemistry , cluster (spacecraft) , vanadium , metal , catalytic oxidation , x ray photoelectron spectroscopy , nuclear magnetic resonance spectroscopy , chemical engineering , stereochemistry , biochemistry , organic chemistry , computer science , engineering , programming language
Catalytic CO oxidation by molecular O 2 is an important model reaction in both the condensed phase and gas‐phase studies. Available gas‐phase studies indicate that noble metal is indispensable in catalytic CO oxidation by O 2 under thermal collision conditions. Herein, we identified the first example of noble‐metal‐free heteronuclear oxide cluster catalysts, the copper–vanadium bimetallic oxide clusters Cu 2 VO 3–5 − for CO oxidation by O 2 . The reactions were characterized by mass spectrometry, photoelectron spectroscopy, and density functional calculations. The dynamic nature of the Cu−Cu unit in terms of the electron storage and release is the driving force to promote CO oxidation and O 2 activation during the catalysis.