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Fire‐Retardant and Thermally Insulating Phenolic‐Silica Aerogels
Author(s) -
Yu ZhiLong,
Yang Ning,
ApostolopoulouKalkavoura Varvara,
Qin Bing,
Ma ZhiYuan,
Xing WeiYi,
Qiao Chan,
Bergström Lennart,
Antonietti Markus,
Yu ShuHong
Publication year - 2018
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201711717
Energy efficient buildings require materials with a low thermal conductivity and a high fire resistance. Traditional organic insulation materials are limited by their poor fire resistance and inorganic insulation materials are either brittle or display a high thermal conductivity. Herein we report a mechanically resilient organic/inorganic composite aerogel with a thermal conductivity significantly lower than expanded polystyrene and excellent fire resistance. Co‐polymerization and nanoscale phase separation of the phenol‐formaldehyde‐resin (PFR) and silica generate a binary network with domain sizes below 20 nm. The PFR/SiO 2 aerogel can resist a high‐temperature flame without disintegration and prevents the temperature on the non‐exposed side from increasing above the temperature critical for the collapse of reinforced concrete structures.