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Thioketone‐Directed Palladium(II)‐Catalyzed C−H Arylation of Ferrocenes with Aryl Boronic Acids
Author(s) -
Cai ZhongJian,
Liu ChenXu,
Gu Qing,
You ShuLi
Publication year - 2018
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201711451
Subject(s) - palladium , aryl , chemistry , catalysis , combinatorial chemistry , chelation , surface modification , organic chemistry , alkyl
A palladium(II)‐catalyzed thioketone‐chelation‐assisted direct C−H arylation of ferrocenes is described. With thioketone as an efficient directing group, various monoaryl‐ and diaryl‐substituted thiocarbonylferrocenes were obtained by palladium‐catalyzed direct C−H functionalization in high yields under mild and base‐free reaction conditions. Furthermore, the arylated thiocarbonylferrocene could undergo diverse transformations.