Distal Weak Coordination of Acetamides in Ruthenium(II)‐Catalyzed C−H Activation Processes | Zendy

Bu Qingqing | Zendy; Rogge Torben | Zendy; Kotek Vladislav | Zendy; Ackermann Lutz | Zendy

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Distal Weak Coordination of Acetamides in Ruthenium(II)‐Catalyzed C−H Activation Processes

Author(s) -

Bu Qingqing,

Rogge Torben,

Kotek Vladislav,

Ackermann Lutz

Publication year - 2018

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201711108

Subject(s) - ruthenium , catalysis , electrophile , chemistry , alkyne , combinatorial chemistry , surface modification , medicinal chemistry , stereochemistry , organic chemistry

C−H activations with challenging arylacetamides were accomplished by versatile ruthenium(II) biscarboxylate catalysis. The distal C−H functionalization offers ample scope—including twofold oxidative C−H functionalizations and alkyne hydroarylations—through facile base‐assisted internal electrophilic‐type substitution (BIES) C−H ruthenation by weak O ‐coordination.

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