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Inside Cover: C 3 ‐Symmetric Tricyclo[2.2.1.0 2,6 ]heptane‐3,5,7‐triol (Angew. Chem. Int. Ed. 48/2017)
Author(s) -
Kozel Volodymyr,
Daniliuc ConstantinGabriel,
Kirsch Peer,
Haufe Günter
Publication year - 2017
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201710815
Subject(s) - enantiopure drug , triol , heptane , cover (algebra) , dopant , reagent , simple (philosophy) , combinatorial chemistry , chemistry , materials science , organic chemistry , enantioselective synthesis , diol , catalysis , optoelectronics , engineering , mechanical engineering , philosophy , doping , epistemology
The smallest tricyclic C 3 ‐symmetric triol was obtained as a racemate in a simple one‐pot synthesis from readily available commercial starting materials and reagents. Classical resolution provided the propeller‐like enantiopure triols, which have a high potential for application in asymmetric synthesis, molecular recognition, and materials science. In their Communication on page 15456 ff., G. Haufe et al. provide more details, including the synthesis of a chiral dopant for liquid crystals.