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Iron(II)‐Catalyzed Direct Synthesis of NH Sulfoximines from Sulfoxides
Author(s) -
Yu Hao,
Li Zhen,
Bolm Carsten
Publication year - 2018
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201710498
Subject(s) - hydroxylamine , catalysis , triflic acid , substrate (aquarium) , salt (chemistry) , chemistry , scope (computer science) , combinatorial chemistry , organic chemistry , computer science , biology , programming language , ecology
Free NH‐sulfoximines were directly prepared from sulfoxides through iron catalysis by applying a readily available, shelf‐stable hydroxylamine triflic acid salt. No additional oxidant is needed, and the substrate scope is broad, including a range of heterocyclic compounds.