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Ligand‐ and Solvent‐Controlled Regio‐ and Chemodivergent Carbonylative Reactions
Author(s) -
Peng JinBao,
Wu XiaoFeng
Publication year - 2018
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201709807
Subject(s) - carbonylation , selectivity , chemistry , ligand (biochemistry) , combinatorial chemistry , solvent , organic chemistry , catalysis , carbon monoxide , receptor , biochemistry
The development of highly selective procedures is one of the core goals in organic chemistry. Among the known organic transformations, carbonylation reactions present an ideal choice for the preparation of carbonyl‐containing compounds. In this review, the recent achievements on the control of the selectivity for carbonylation reactions have been summarized. The effects of ligands, solvents, and bases on the selectivity are been discussed.