Selective Functionalization of Aromatic C(sp 2 )−H Bonds in the Presence of Benzylic C(sp 3 )−H Bonds by Electron‐Deficient Carbenoids Generated from 4‐Acyl‐1‐Sulfonyl‐1,2,3‐Triazoles | Zendy

Miura Tomoya | Zendy; Zhao Qiang | Zendy; Murakami Masahiro | Zendy

Premium

Selective Functionalization of Aromatic C(sp 2 )−H Bonds in the Presence of Benzylic C(sp 3 )−H Bonds by Electron‐Deficient Carbenoids Generated from 4‐Acyl‐1‐Sulfonyl‐1,2,3‐Triazoles

Author(s) -

Miura Tomoya,

Zhao Qiang,

Murakami Masahiro

Publication year - 2017

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201709384

Subject(s) - rhodium , chemistry , benzene , surface modification , acceptor , sulfonyl , medicinal chemistry , electron deficiency , catalysis , stereochemistry , organic chemistry , physics , alkyl , condensed matter physics

A rhodium(II)‐catalyzed reaction of newly prepared 4‐acyl‐1‐sulfonyl‐1,2,3‐triazoles with benzene, and its derivatives, is investigated. Acceptor/acceptor carbenoids generated from 4‐acyltriazoles undergo selective insertion at aromatic C(sp 2 )−H bonds in the presence of benzylic C(sp 3 )−H bonds to produce N ‐sulfonylenaminones.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research