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Diols as Dienophiles: Bridged Carbocycles via Ruthenium(0)‐Catalyzed Transfer Hydrogenative Cycloadditions of Cyclohexadiene or Norbornadiene
Author(s) -
Sato Hiroki,
Fukaya Keisuke,
Poudel Binit Sharma,
Krische Michael J.
Publication year - 2017
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201708189
Subject(s) - norbornadiene , ruthenium , bicyclic molecule , catalysis , chemistry , diol , ring (chemistry) , medicinal chemistry , organic chemistry
Highly exo‐selective ruthenium(0) catalyzed transfer hydrogenative cycloadditions of 1,2‐diols with cyclohexadiene or norbornadiene are described. Novel bridged bicyclic ring systems are accessible from the diol, α‐ketol or 1,2‐dione oxidation levels with complete control of diastereoselectivity.