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Back Cover: Synthesis and Reactivity of Fluoroalkyl Copper Complexes by the Oxycupration of Tetrafluoroethylene (Angew. Chem. Int. Ed. 39/2017)
Author(s) -
Ohashi Masato,
Adachi Takuya,
Ishida Naoyoshi,
Kikushima Kotaro,
Ogoshi Sensuke
Publication year - 2017
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201707624
Subject(s) - tetrafluoroethylene , copper , reactivity (psychology) , aryl , alkyl , polymer chemistry , chemistry , int , cover (algebra) , organic chemistry , copolymer , polymer , medicine , mechanical engineering , alternative medicine , pathology , computer science , engineering , operating system
Copper(I)‐mediated generation of −OCF 2 CF 2 − moieties through the oxycupration of tetrafluoroethylene using either copper aryloxides or alkoxides is described by S. Ogoshi et al. on page 11911 ff. The key intermediates, 2‐aryloxy‐ and 2‐alkyloxy‐1,1,2,2‐tetrafluoroethyl copper complexes, were obtained and subsequently reacted with aryl iodides to afford ROCF 2 CF 2 Ar (R=aryl or alkyl) in high yields.