Copper‐Catalyzed Synthesis and Applications of Yndiamides | Zendy

Mansfield Steven J. | Zendy; Christensen Kirsten E. | Zendy; Thompson Amber L. | Zendy; Ma Kai | Zendy; Jones Michael W. | Zendy; Mekareeya Aroonroj | Zendy; Anderson Edward A. | Zendy

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Copper‐Catalyzed Synthesis and Applications of Yndiamides

Author(s) -

Mansfield Steven J.,

Christensen Kirsten E.,

Thompson Amber L.,

Ma Kai,

Jones Michael W.,

Mekareeya Aroonroj,

Anderson Edward A.

Publication year - 2017

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201706915

Subject(s) - alkyne , catalysis , copper , nucleophile , combinatorial chemistry , chemistry , transition metal , coupling (piping) , nitrogen , metal , organic chemistry , materials science , metallurgy

The first synthetic route to yndiamides, a novel class of double aza‐substituted alkyne, has been established by the copper(I)‐catalyzed cross‐coupling of 1,1‐dibromoenamides with nitrogen nucleophiles. The utility of these compounds is demonstrated in a range of transition‐metal‐catalyzed and acid‐catalyzed transformations to afford a wide variety of 1,2‐diamide functionalized products.

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