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Back Cover: SuFEx‐Based Polysulfonate Formation from Ethenesulfonyl Fluoride–Amine Adducts (Angew. Chem. Int. Ed. 37/2017)
Author(s) -
Wang Hua,
Zhou Feng,
Ren Gerui,
Zheng Qinheng,
Chen Hongli,
Gao Bing,
Klivansky Liana,
Liu Yi,
Wu Bin,
Xu Qingfeng,
Lu Jianmei,
Sharpless K. Barry,
Wu Peng
Publication year - 2017
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201706481
Subject(s) - fluoride , adduct , chemistry , catalysis , polymer chemistry , sulfur , bisphenol a , int , condensation polymer , amine gas treating , organic chemistry , medicinal chemistry , inorganic chemistry , computer science , epoxy , operating system
The sulfur(VI) fluoride exchange (SuFEx)‐based polycondensation reaction between bisalkylsulfonyl fluorides and bisphenol bis( tert ‐butyldimethylsilyl) ethers using [Ph 3 P=N−PPh 3 ]+[HF 2 ] − as the catalyst was been developed. As described by P. Wu, K. B. Sharpless et al. in their Communication on page 11203 ff., polysulfonates synthesized by this method can be further functionalized using click‐chemistry‐based transformations orthogonal to SuFEx.