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Group 6 Transition‐Metal/Boron Frustrated Lewis Pair Templates Activate N 2 and Allow its Facile Borylation and Silylation
Author(s) -
Simonneau Antoine,
Turrel Raphaël,
Vendier Laure,
Etienne Michel
Publication year - 2017
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201706226
Subject(s) - borylation , frustrated lewis pair , borane , chemistry , silylation , moiety , boranes , transition metal , reactivity (psychology) , boron , adduct , lewis acids and bases , template , hydroboration , crystallography , stereochemistry , medicinal chemistry , catalysis , nanotechnology , organic chemistry , materials science , aryl , medicine , alkyl , alternative medicine , pathology
The reaction of trans ‐[M(N 2 ) 2 (dppe) 2 ] (M=Mo, 1 Mo , M=W, 1 W ) with B(C 6 F 5 ) 3 ( 2 ) provides the adducts [(dppe) 2 M=N=N‐B(C 6 F 5 ) 3 ] ( 3 ) which can be regarded as M/B transition‐metal frustrated Lewis pair (TMFLP) templates activating dinitrogen. Easy borylation and silylation of the activated dinitrogen ligands in complexes 3 with a hydroborane and hydrosilane occur by splitting of the B−H and Si−H bonds between the N 2 moiety and the perfluoroaryl borane. This reactivity of 3 is reminiscent of conventional frustrated Lewis pair chemistry and constitutes an unprecedented approach for the functionalization of dinitrogen.