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Stereospecificity in Intramolecular Photoredox Reactions of Naphthoquinones: Enantioselective Total Synthesis of (−)‐Spiroxin C
Author(s) -
Ando Yoshio,
Hanaki Atsuko,
Sasaki Ryota,
Ohmori Ken,
Suzuki Keisuke
Publication year - 2017
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201705562
Subject(s) - intramolecular force , enantioselective synthesis , stereospecificity , chemistry , total synthesis , stereochemistry , combinatorial chemistry , organic chemistry , catalysis
Intramolecular photoredox reactions of naphthoquinone derivatives were found to proceed in a stereospecific manner. This method was used as a basis for the enantioselective total synthesis of (−)‐spiroxin C.