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An Interconnected Ternary MIn 2 S 4 (M=Fe, Co, Ni) Thiospinel Nanosheet Array: A Type of Efficient Platinum‐Free Counter Electrode for Dye‐Sensitized Solar Cells
Author(s) -
Hou Wenjing,
Xiao Yaoming,
Han Gaoyi
Publication year - 2017
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201705399
Subject(s) - nanosheet , dye sensitized solar cell , auxiliary electrode , materials science , electrolyte , electrode , ternary operation , platinum , tin oxide , chemical engineering , energy conversion efficiency , nanotechnology , optoelectronics , doping , chemistry , catalysis , organic chemistry , computer science , engineering , programming language
The ternary iron‐group thiospinels of metal diindium sulfides (MIn 2 S 4 , M=Fe, Co, Ni) with a vertically aligned nanosheet array structure are fabricated through an in situ solvothermal method on F‐doped tin oxide (FTO) substrates, which are employed as one type of platinum (Pt)‐free counter electrodes (CEs) in structure‐dependent dye‐sensitized solar cells (DSSCs). A DSSC assembled with ternary CoIn 2 S 4 CE achieves an photoelectric conversion efficiency (PCE) of 8.83 %, outperforming than that of FeIn 2 S 4 (7.18 %) and NiIn 2 S 4 (8.27 %) CEs under full sunlight illumination (100 mW cm −2 , AM 1.5 G), which is also comparable with that of the Pt CE (8.19 %). Putting aside that the interconnected nanosheet array provides fast electron transfer and electrolyte diffusion channels, the highest PCE of CoIn 2 S 4 based DSSC results from its largest specific surface area (144.07 m 2 g −1 ), providing abundant active sites and the largest electron injection efficiency from CE to electrolyte.