A T‐Shaped Nickel(I) Metalloradical Species | Zendy

Yoo Changho | Zendy; Lee Yunho | Zendy

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A T‐Shaped Nickel(I) Metalloradical Species

Author(s) -

Yoo Changho,

Lee Yunho

Publication year - 2017

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201704487

Subject(s) - nickel , homolysis , steric effects , ligand (biochemistry) , reactivity (psychology) , chemistry , pincer movement , cleavage (geology) , crystallography , stereochemistry , materials science , radical , catalysis , organic chemistry , medicine , biochemistry , receptor , alternative medicine , pathology , fracture (geology) , composite material

A T‐shaped Ni I complex was synthesized using a rigid acridane‐based pincer ligand to prepare a metalloradical center. Structural data displays a nickel ion is embedded in the plane of a PNP ligand. Having a sterically exposed half‐filled d x 2 - y 2orbital, this three‐coordinate Ni I species reveals unique open‐shell reactivity including the homolytic cleavage of various σ‐bonds, such as H−H, N−N, and C−C.

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