Premium
Cation‐Driven Self‐Assembly of a Gold(I)‐Based Metallo‐Tweezer
Author(s) -
Ibáñez Susana,
Poyatos Macarena,
Peris Eduardo
Publication year - 2017
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201704359
Subject(s) - stacking , titration , fluorescence , chemistry , ion , self assembly , crystallography , spectroscopy , supramolecular chemistry , inorganic chemistry , organic chemistry , crystal structure , physics , quantum mechanics
A combination of self‐complementary π–π‐stacking interactions and metallophilic interactions triggered the self‐assembly of a new digold(I) metallo‐tweezer in the presence of several types of M + ions. Titrations by fluorescence spectroscopy enabled the determination of the association constants of the resulting inclusion duplex complexes.