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Synthesis, Solid‐State Structure, and Bonding Analysis of a Homoleptic Beryllium Azide
Author(s) -
Naglav Dominik,
Tobey Briac,
Lyhs Benjamin,
Römer Beate,
Bläser Dieter,
Wölper Christoph,
Jansen Georg,
Schulz Stephan
Publication year - 2017
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201703147
Subject(s) - homoleptic , beryllium , azide , chemistry , solid state , crystallography , organic chemistry , metal
[Ph 4 P] 2 [Be(N 3 ) 4 ] ( 1 ) and [PNP] 2 [Be(N 3 ) 4 ] ( 2 ; PNP=Ph 3 PNPPh 3 ) were synthesized by reacting Be(N 3 ) 2 with [Ph 4 P]N 3 and [PNP]N 3 . Compound 1 represents the first structurally characterized homoleptic beryllium azide. The electronic structure and bonding situation in the tetraazidoberyllate dianion [Be(N 3 ) 4 ] 2− were investigated by quantum‐chemical calculations (NPA, ELF, LOL).