Synthesis, Solid‐State Structure, and Bonding Analysis of a Homoleptic Beryllium Azide | Zendy

Naglav Dominik | Zendy; Tobey Briac | Zendy; Lyhs Benjamin | Zendy; Römer Beate | Zendy; Bläser Dieter | Zendy; Wölper Christoph | Zendy; Jansen Georg | Zendy; Schulz Stephan | Zendy

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Synthesis, Solid‐State Structure, and Bonding Analysis of a Homoleptic Beryllium Azide

Author(s) -

Naglav Dominik,

Tobey Briac,

Lyhs Benjamin,

Römer Beate,

Bläser Dieter,

Wölper Christoph,

Jansen Georg,

Schulz Stephan

Publication year - 2017

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201703147

Subject(s) - homoleptic , beryllium , azide , chemistry , solid state , crystallography , organic chemistry , metal

[Ph 4 P] 2 [Be(N 3 ) 4 ] ( 1 ) and [PNP] 2 [Be(N 3 ) 4 ] ( 2 ; PNP=Ph 3 PNPPh 3 ) were synthesized by reacting Be(N 3 ) 2 with [Ph 4 P]N 3 and [PNP]N 3 . Compound 1 represents the first structurally characterized homoleptic beryllium azide. The electronic structure and bonding situation in the tetraazidoberyllate dianion [Be(N 3 ) 4 ] 2− were investigated by quantum‐chemical calculations (NPA, ELF, LOL).

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