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Theoretical Treatment of CH 3 NH 3 PbI 3 Perovskite Solar Cells
Author(s) -
Yun Sining,
Zhou Xiao,
Even Jacky,
Hagfeldt Anders
Publication year - 2017
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201702660
Subject(s) - perovskite (structure) , current (fluid) , hysteresis , materials science , ionic bonding , ferroelectricity , diffusion , halide , engineering physics , optoelectronics , nanotechnology , chemical physics , perovskite solar cell , energy conversion efficiency , condensed matter physics , ion , dielectric , chemistry , electrical engineering , inorganic chemistry , crystallography , physics , thermodynamics , engineering , organic chemistry
Hybrid halide perovskite solar cells (PSCs) giving over 22 % power conversion efficiencies (PCEs) have attracted considerable attention. Although perovskite plays a significant role in the operation of PSCs, the fundamental theories associated with perovskites have not been resolved in spite of the increase in research. In this Minireview, we assess the current understanding, based on the first‐principles calculations, of structural and electronic properties, defects, ionic diffusion, and shift current for CH 3 NH 3 PbI 3 perovskite, and the effect of ionic transport on the hysteresis of current–voltage curves in PSCs. The shift current connected to the possible presence of ferroelectricity is also discussed. The current state‐of‐the‐art and some open questions regarding PSCs are also highlighted, and the benefits, challenges, and potentials of perovskite for use in PSCs are stressed.