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Inside Cover: Efficient Palladium‐Catalyzed Alkoxycarbonylation of Bulk Industrial Olefins Using Ferrocenyl Phosphine Ligands (Angew. Chem. Int. Ed. 19/2017)
Author(s) -
Dong Kaiwu,
Sang Rui,
Fang Xianjie,
Franke Robert,
Spannenberg Anke,
Neumann Helfried,
Jackstell Ralf,
Beller Matthias
Publication year - 2017
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201702485
Subject(s) - alkene , phosphine , steric effects , catalysis , palladium , ligand (biochemistry) , chemistry , carbonylation , medicinal chemistry , organic chemistry , polymer chemistry , combinatorial chemistry , carbon monoxide , biochemistry , receptor
Game‐changing ligand design for alkene alkoxycarbonylations: In their Communication on page 5267 ff., M. Beller and co‐workers present a novel class of ferrocenyl ligands for improved alkene carbonylations. These phosphines with sterically hindered and amphoteric groups on the P atoms actively take part in the catalysis. They are easily synthesized and display higher activity and durability in alkoxycarbonylations of bulk olefins under milder conditions.