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Importance of Inherent Substrate Reactivity in Enzyme‐Promoted Carbocation Cyclization/Rearrangements
Author(s) -
Tantillo Dean J.
Publication year - 2017
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201702363
Subject(s) - carbocation , reactivity (psychology) , substrate (aquarium) , chemistry , enzyme , stereochemistry , computational chemistry , organic chemistry , biology , ecology , medicine , alternative medicine , pathology
The importance of inherent substrate reactivity for terpene synthase enzymes is discussed, with a focus on recent experimental tests of predictions derived from computations on gas‐phase reactivity of carbocations.