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Carbonylations with CO 2 as the CO Source and Reactivity Modifier
Author(s) -
Dong Kaiwu,
Wu XiaoFeng
Publication year - 2017
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201702292
Subject(s) - reactivity (psychology) , hydroformylation , aryl , chemistry , carbonylation , organic chemistry , carbon monoxide , catalysis , alkyl , medicine , rhodium , alternative medicine , pathology
A CO surrogate : In two recent studies, CO 2 has not only been applied as a CO source in the hydroformylation of alkenes and the carbonylative Hiyama–Denmark coupling of aryl iodides, but more interestingly it also attenuates or improves the reactivity of the reactants.