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Forging C−C Bonds Through Decarbonylation of Aryl Ketones
Author(s) -
Somerville Rosie J.,
Martin Ruben
Publication year - 2017
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201702188
Subject(s) - decarbonylation , chemistry , aryl , bond cleavage , nickel , cleave , stereochemistry , organic chemistry , catalysis , enzyme , alkyl
The ability of nickel to cleave strong σ‐bonds is again in the spotlight after a recent report that demonstrates the feasibility of using nickel complexes to promote decarbonylation of diaryl ketones. This transformation involves the cleavage of two strong C−C(O) bonds and avoids the use of noble metals, hence reinforcing the potential of decarbonylation as a technique for forging C−C bonds.
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