Hydroxoiridium‐Catalyzed Hydroalkylation of Terminal Alkenes with Ureas by C(sp 3 )−H Bond Activation | Zendy

Yamauchi Daisuke | Zendy; Nishimura Takahiro | Zendy; Yorimitsu Hideki | Zendy

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Hydroxoiridium‐Catalyzed Hydroalkylation of Terminal Alkenes with Ureas by C(sp 3 )−H Bond Activation

Author(s) -

Yamauchi Daisuke,

Nishimura Takahiro,

Yorimitsu Hideki

Publication year - 2017

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201702169

Subject(s) - catalysis , alkylation , chemistry , terminal (telecommunication) , medicinal chemistry , stereochemistry , organic chemistry , telecommunications , computer science

Direct alkylation of a methyl group, on di‐ and trisubstituted ureas, with terminal alkenes by C(sp 3 )−H bond activation proceeded in the presence of a hydroxoiridium/bisphosphine catalyst to give high yields of the corresponding addition products. The hydroxoiridium/bisphosphine complex generates an amidoiridium intermediate by reaction with ureas having an N−H bond.

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