Binding CO 2  by a Cr 8  Metallacrown | Zendy

VitóricaYrezábal Iñigo J. | Zendy; Sava Daniel Florin | Zendy; Timco Grigore A. | Zendy; Brown Martyn S. | Zendy; Savage Mathew | Zendy; Godfrey Harry G. W. | Zendy; Moreau Florian | Zendy; Schröder Martin | Zendy; Siperstein Flor | Zendy; Brammer Lee | Zendy; Yang Sihai | Zendy; Attfield Martin P. | Zendy; McDouall Joseph J. W. | Zendy; Winpenny Richard E. P. | Zendy

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Binding CO 2 by a Cr 8 Metallacrown

Author(s) -

VitóricaYrezábal Iñigo J.,

Sava Daniel Florin,

Timco Grigore A.,

Brown Martyn S.,

Savage Mathew,

Godfrey Harry G. W.,

Moreau Florian,

Schröder Martin,

Siperstein Flor,

Brammer Lee,

Yang Sihai,

Attfield Martin P.,

McDouall Joseph J. W.,

Winpenny Richard E. P.

Publication year - 2017

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201701726

Subject(s) - crystallography , selectivity , diffraction , chemistry , absorption (acoustics) , center (category theory) , x ray crystallography , crystal (programming language) , single crystal , materials science , stereochemistry , physics , optics , catalysis , organic chemistry , programming language , computer science , composite material

The {Cr 8 } metallacrown [CrF(O 2 C t Bu) 2 ] 8 , containing a F‐lined internal cavity, shows high selectivity for CO 2 over N 2 . DFT calculations and absorption studies support the multiple binding of F‐groups to the C‐center of CO 2 (C⋅⋅⋅F 3.190(9)–3.389(9) Å), as confirmed by single‐crystal X‐ray diffraction.

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