Premium
B(C 6 F 5 ) 3 ‐Catalyzed Ring Opening and Isomerization of Unactivated Cyclopropanes
Author(s) -
Zhang ZiYu,
Liu ZhiYun,
Guo RuiTing,
Zhao YuQuan,
Li Xiang,
Wang XiaoChen
Publication year - 2017
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201700864
Subject(s) - isomerization , ring (chemistry) , catalysis , terminal (telecommunication) , chemistry , medicinal chemistry , stereochemistry , organic chemistry , computer science , telecommunications
Catalytic amounts of B(C 6 F 5 ) 3 promote the ring opening and subsequent isomerization of a series of unactivated cyclopropanes to afford terminal olefins in good yields when a hydrosilane and 2,6‐dibromopyridine are employed as additives.