Facile Modulation of FLP Properties: A Phosphinylvinyl Grignard Reagent and Ga/P‐ and In/P 2 ‐Based Frustrated Lewis Pairs | Zendy

Backs Jana | Zendy; Lange Merten | Zendy; Possart Josephine | Zendy; Wollschläger Agnes | Zendy; MückLichtenfeld Christian | Zendy; Uhl Werner | Zendy

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Facile Modulation of FLP Properties: A Phosphinylvinyl Grignard Reagent and Ga/P‐ and In/P 2 ‐Based Frustrated Lewis Pairs

Author(s) -

Backs Jana,

Lange Merten,

Possart Josephine,

Wollschläger Agnes,

MückLichtenfeld Christian,

Uhl Werner

Publication year - 2017

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201612485

Subject(s) - transmetalation , chemistry , frustrated lewis pair , reagent , atom (system on chip) , lewis acids and bases , chelation , metal , stereochemistry , medicinal chemistry , polymer chemistry , organic chemistry , catalysis , computer science , embedded system

An Al/P‐based frustrated Lewis pair (FLP) reacted with PhMgCl by an unexpected transmetalation and formation of a phosphinylvinyl Grignard reagent. This compound is well suited for the transfer of the basic FLP component to other Lewis acidic metal atoms and allowed the generation of a Ga/P and an In/P 2 FLP. The Ga FLP showed a behavior different to that of the corresponding Al FLP, the In FLP allowed the chelating coordination of an Au atom by Au−Cl bond activation.

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