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Au/La 2 Ti 2 O 7 Nanostructures Sensitized with Black Phosphorus for Plasmon‐Enhanced Photocatalytic Hydrogen Production in Visible and Near‐Infrared Light
Author(s) -
Zhu Mingshan,
Cai Xiaoyan,
Fujitsuka Mamoru,
Zhang Junying,
Majima Tetsuro
Publication year - 2017
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201612315
Subject(s) - photocatalysis , materials science , visible spectrum , plasmon , photochemistry , spectroscopy , optoelectronics , infrared , absorption (acoustics) , hydrogen production , hydrogen , optics , catalysis , chemistry , physics , biochemistry , organic chemistry , quantum mechanics , composite material
Efficient utilization of solar energy is a high‐priority target and the search for suitable materials as photocatalysts that not only can harvest the broad wavelength of solar light, from UV to near‐infrared (NIR) region, but also can achieve high and efficient solar‐to‐hydrogen conversion is one of the most challenging missions. Herein, using Au/La 2 Ti 2 O 7 (BP‐Au/LTO) sensitized with black phosphorus (BP), a broadband solar response photocatalyst was designed and used as efficient photocatalyst for H 2 production. The optimum H 2 production rates of BP‐Au/LTO were about 0.74 and 0.30 mmol g −1 h −1 at wavelengths longer than 420 nm and 780 nm, respectively. The broad absorption of BP and plasmonic Au contribute to the enhanced photocatalytic activity in the visible and NIR light regions. Time‐resolved diffuse reflectance spectroscopy revealed efficient interfacial electron transfer from excited BP and Au to LTO which is in accordance with the observed high photoactivities.