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Water Catalysis of the Reaction between Methanol and OH at 294 K and the Atmospheric Implications
Author(s) -
JaraToro Rafael A.,
Hernández Federico J.,
Taccone Raúl A.,
Lane Silvia I.,
Pino Gustavo A.
Publication year - 2017
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201612151
Subject(s) - methanol , relative humidity , catalysis , chemistry , humidity , atmospheric sciences , atmospheric chemistry , reaction rate , environmental chemistry , environmental science , thermodynamics , ozone , organic chemistry , physics
The rate coefficient for the reaction CH 3 OH+OH was determined by means of a relative method in a simulation chamber under quasi‐real atmospheric conditions (294 K, 1 atm of air) and variable humidity or water concentration. Under these conditions, a quadratic dependence of the rate coefficient for the reaction CH 3 OH+OH on the water concentration was found. Thus the catalytic effect of water is not only important at low temperatures, but also at room temperature. The detailed mechanism responsible of the reaction acceleration is still unknown. However, this dependence should be included in the atmospheric global models since it is expected to be important in humid regions as in the tropics. Additionally, it could explain several differences regarding the global and local atmospheric concentration of methanol in tropical areas, for which many speculations about the sinks and sources of methanol have been reported.