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Ni‐Catalyzed Stannylation of Aryl Esters via C−O Bond Cleavage
Author(s) -
Gu Yiting,
Martín Rúben
Publication year - 2017
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201611720
Subject(s) - aryl , bond cleavage , cleavage (geology) , catalysis , reagent , chemistry , combinatorial chemistry , scope (computer science) , heteroatom , polymer chemistry , organic chemistry , materials science , computer science , ring (chemistry) , composite material , alkyl , fracture (geology) , programming language
A Ni‐catalyzed stannylation of aryl esters with air‐ and moisture‐insensitive silylstannyl reagents via Csp2−O cleavage is described. This protocol is characterized by its wide scope, including challenging combinations, thus enabling access to versatile building blocks and orthogonal C−heteroatom bond formations.