Ni‐Catalyzed Stannylation of Aryl Esters via C−O Bond Cleavage | Zendy

Gu Yiting | Zendy; Martín Rúben | Zendy

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Ni‐Catalyzed Stannylation of Aryl Esters via C−O Bond Cleavage

Author(s) -

Gu Yiting,

Martín Rúben

Publication year - 2017

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201611720

Subject(s) - aryl , bond cleavage , cleavage (geology) , catalysis , reagent , chemistry , combinatorial chemistry , scope (computer science) , heteroatom , polymer chemistry , organic chemistry , materials science , computer science , ring (chemistry) , composite material , alkyl , fracture (geology) , programming language

A Ni‐catalyzed stannylation of aryl esters with air‐ and moisture‐insensitive silylstannyl reagents via Csp2−O cleavage is described. This protocol is characterized by its wide scope, including challenging combinations, thus enabling access to versatile building blocks and orthogonal C−heteroatom bond formations.

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