Controllable Remote C−H Bond Functionalization by Visible‐Light Photocatalysis | Zendy

Hu XiaoQiang | Zendy; Chen JiaRong | Zendy; Xiao WenJing | Zendy

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Controllable Remote C−H Bond Functionalization by Visible‐Light Photocatalysis

Author(s) -

Hu XiaoQiang,

Chen JiaRong,

Xiao WenJing

Publication year - 2017

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201611463

Subject(s) - surface modification , photocatalysis , radical , photochemistry , inert , photoredox catalysis , hydrogen atom , visible spectrum , chemistry , hydrogen bond , catalysis , atom transfer radical polymerization , combinatorial chemistry , materials science , organic chemistry , molecule , optoelectronics , group (periodic table) , polymer , polymerization

Remote control : New strategies for the activation of remote C(sp 3 )−H bonds by photoredox‐catalyzed (PC) radical translocation via O‐ and N‐centered radicals have recently been described. These methods enable the controlled and site‐selective functionalization of inert C(sp 3 )−H bonds and provide new opportunities for reaction design (HAT=hydrogen atom transfer).

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