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Inside Back Cover: Superacid‐Catalyzed Trifluoromethylthiolation of Aromatic Amines (Angew. Chem. Int. Ed. 1/2017)
Author(s) -
Bonazaba Milandou Longin Justin Clair,
Carreyre Hélène,
Alazet Sébastien,
Greco Gino,
MartinMingot Agnès,
Nkounkou Loumpangou Célestine,
Ouamba JeanMaurille,
Bouazza Fodil,
Billard Thierry,
Thibaudeau Sébastien
Publication year - 2017
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201611312
Subject(s) - superacid , chemistry , reagent , surface modification , sulfenamide , catalysis , cover (algebra) , organic chemistry , combinatorial chemistry , mechanical engineering , natural rubber , vulcanization , engineering
Superacid activation of N ‐SCF 3 sulfenamide reagents generates diprotonated superelectrophilic species for the trifluoromethylthiolation of aromatic amines, as shown by T. Billard, S. Thibaudeau, and co‐workers in their Communication on page 173 ff. This method can be used for the late‐stage functionalization of complex biomolecules such as alkaloids and steroids.