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Inside Back Cover: Nucleophilic Transfer Reactions of the [Si(C 2 F 5 ) 3 ] − Moiety (Angew. Chem. Int. Ed. 52/2016)
Author(s) -
Schwarze Nico,
Steinhauer Simon,
Neumann Beate,
Stammler HansGeorg,
Hoge Berthold
Publication year - 2016
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201611311
Subject(s) - moiety , nucleophile , chemistry , silanes , trifluoromethyl , cover (algebra) , tris , nucleophilic substitution , polymer chemistry , medicinal chemistry , stereochemistry , organic chemistry , catalysis , biochemistry , alkyl , silane , mechanical engineering , engineering
Whereas tris(trifluoromethyl)silanes tend to decompose violently at room temperature, the corresponding pentafluoroethyl derivatives are thermostable compounds. Preparative synthesis of Li[Si(C 2 F 5 ) 3 ] enabled efficient nucleophilic transfer of the Si(C 2 F 5 ) 3 unit onto main‐group and transition‐metal compounds as well as organic scaffolds, as shown by B. Hoge and co‐workers in two Communications on page 16156 ff. and on page 16161 ff.