Photoarylation of Iodocarboranes with Unactivated (Hetero)Arenes: Facile Synthesis of 1,2‐[(Hetero)Aryl]  n  ‐ o ‐Carboranes ( n =1,2) and  o ‐Carborane‐Fused Cyclics | Zendy

Ni Hangcheng | Zendy; Qiu Zaozao | Zendy; Xie Zuowei | Zendy

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Photoarylation of Iodocarboranes with Unactivated (Hetero)Arenes: Facile Synthesis of 1,2‐[(Hetero)Aryl] n ‐ o ‐Carboranes ( n =1,2) and o ‐Carborane‐Fused Cyclics

Author(s) -

Ni Hangcheng,

Qiu Zaozao,

Xie Zuowei

Publication year - 2017

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201610810

Subject(s) - aryl , chemistry , combinatorial chemistry , transition metal , carbon fibers , medicinal chemistry , organic chemistry , materials science , catalysis , alkyl , composite number , composite material

Photoarylation of iodocarboranes with unactivated arenes/heteroarenes at room temperature has been achieved, for the first time, thus leading to the facile synthesis of a large variety of cage carbon mono(hetero)arylated and di(hetero)arylated o‐carboranes. This work represents a clean, efficient, transition‐metal‐free, and cheap synthesis of functionalized carboranes, which has significant advantages over the known methods.

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