Nickel(0)‐Mediated Transformation of Tetrafluoroethylene and Vinylarenes into Fluorinated Cyclobutyl Compounds | Zendy

Ohashi Masato | Zendy; Ueda Yuta | Zendy; Ogoshi Sensuke | Zendy

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Nickel(0)‐Mediated Transformation of Tetrafluoroethylene and Vinylarenes into Fluorinated Cyclobutyl Compounds

Author(s) -

Ohashi Masato,

Ueda Yuta,

Ogoshi Sensuke

Publication year - 2017

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201610047

Subject(s) - tetrafluoroethylene , moiety , fluorine , styrene , amine gas treating , chemistry , nickel , polymer chemistry , organic chemistry , copolymer , polymer

In the presence of Ni 0 /PCy 3 , styrene was found to participate in oxidative cyclization with tetrafluoroethylene, thus leading to the corresponding nickelacycle with a unique η 3 ‐π‐benzyl structure. In addition, the flexibility of the coordination mode in the η 3 ‐benzyl moiety allowed the partially fluorinated nickelacycle to undergo unprecedented amine‐induced α‐fluorine elimination, thus leading to the construction of a fluorinated cyclobutyl skeleton.

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