Inside Back Cover: Fullerene‐Based Macro‐Heterocycle Prepared through Selective Incorporation of Three N and Two O Atoms into C 60  (Angew. Chem. Int. Ed. 47/2016) | Zendy

Li Yanbang | Zendy; Zhang Gaihong | Zendy; Wang Dian | Zendy; Xu Beidi | Zendy; Xu Dan | Zendy; Lou Ning | Zendy; Gan Liangbing | Zendy

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Inside Back Cover: Fullerene‐Based Macro‐Heterocycle Prepared through Selective Incorporation of Three N and Two O Atoms into C 60 (Angew. Chem. Int. Ed. 47/2016)

Author(s) -

Li Yanbang,

Zhang Gaihong,

Wang Dian,

Xu Beidi,

Xu Dan,

Lou Ning,

Gan Liangbing

Publication year - 2016

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Reports

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201609559

Subject(s) - fullerene , chemistry , cleavage (geology) , molecule , piperidine , reactivity (psychology) , copper , bond cleavage , ion , cover (algebra) , fluoride , planar , crystallography , stereochemistry , polymer chemistry , inorganic chemistry , organic chemistry , materials science , mechanical engineering , computer science , engineering , medicine , alternative medicine , computer graphics (images) , pathology , fracture (geology) , composite material , catalysis

Macrocyclic compounds have been extensively studied because of their widespread applications. Most classical macrocyclic compounds are planar molecules. In their Communication on page 14590 ff., L. B. Gan and co‐workers report a N,O‐heterocycle created on the C 60 cage skeleton through a multistep procedure, which includes repeated PCl 5 ‐induced hydroxylamino N−O bond cleavage, and also piperidine‐induced peroxo O−O bond cleavage. The fullerene‐based macrocycle showed unique reactivity towards fluoride ions and copper salts.

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